byte[] bytes = { 0, 0, 0, 25 };

// If the system architecture is little-endian (that is, little end first),
// reverse the byte array.
if (BitConverter.IsLittleEndian)
    Array.Reverse(bytes);

int i = BitConverter.ToInt32(bytes, 0);
Console.WriteLine("int: {0}", i);
// Output: int: 25